高憲明 教授

Hsien-Ming Kao

　

電話: (03) 4227151 分機 65932; 65939; 65937

E-mail: hmkao@cc.ncu.edu.tw

　

台灣大學化學系學士(1988)，台灣大學化學系碩士(1990)，美國紐約州立大學石溪分校化學博士(1998)，美國聖路易市華盛頓大學博士後研究(1998-1999) ，中央大學化學系助理教授(1999-2003)、副教授(2003-2007)、教授(2007-) ，台灣磁共振學會理事 (2005-2007)，中央大學研究傑出獎(2006, 2007)，第九屆清華化學科技文教基金會傑出青年學者獎 (2008)

　

歡迎參觀分子篩觸媒實驗室(03-4227151 分機 65919)

500 MHz Solid State NMR  (03-4227151 分機 65939)

post-doc. position available in Prof. Hsien-Ming Kao's lab

研究興趣

1.      奈米孔洞觸媒材料之合成鑑定與其在催化及綠色化學上之應用

2.      高能鋰離子與燃料電池材料之設計開發與應用

3.      奈米複合高分子材料之研發

4.      固態核磁共振技術之開發與應用

                   奈米觸媒

             (中孔洞材料)

電池高能材料

(高分子電解質)

沸石脫鋁

     500 MHz Solid-State NMR

　

書籍著作

1.      何雍, 高憲明 “全方位無機化學”, 第七版

2.      何雍, 高憲明 “物理化學分類題庫”, 第七版

3.      何雍, 高憲明 “儀器分析總整理”, 第七版

　

歷年計畫

國科會個人計畫 (each year)

國科會大學學術追求卓越發展延續計畫(整合型)多年期計畫: 尖端材料的奈米基礎科學研究-奈米科技於觸媒之應用 (2004 – 2008)

國家型整合計畫：奈米材料於甲醇燃料電池的應用  (2005 – 2008)

國家型能源整合計畫：高導電之高分子電解質之製備 (2005 – 2008)

工研院創新前瞻計畫:奈米觸媒之分項子計畫: 奈米觸媒去硫計畫 (2004 – 2006)

工研院創新前瞻計畫: 強吸水性沸石薄膜之製備與應用 (2004 – 2007)

工研院創新前瞻計畫: 高活性鉑合金/碳材奈米複合物作為燃料電池之電極觸媒的合成與鑑定 (2003 – 2005)

長春石化產學合作: 奈米黏土表面修飾 (2004 – 2005)

勝光科技產學合作: 設計與開發有機無機複合材料之固態高分子電解質 (2003 – 2004)

　
代表論文 (2004~present)

1.   Hsien-Ming Kao*, Chia-Hsiu Liao, Tzu-Ti Hung, Yu-Chi Pan, Anthony S. T. Chiang, “Direct Synthesis and Solid-State NMR Characterization of Cubic Mesoporous Silica SBA-1 Functionalized with Phenyl Groups”, Chem. Mater., 2008, 20, 2412.

2. Hsien-Ming Kao*, Lung-Ping Lee, Arudra Palani, “13C CPMAS NMR Spectroscopy as a Versatile and Quantitative Tool for Determination of Mercury Adsorption Capacity in Thiol-functionalized Mesoporous Silica SBA-1”, Anal. Chem., 2008, 80, 3016.

3. Hsien-Ming Kao*, Chia-Hsiu Liao, Arudra Palani, Yi-Chen Liao, “One-pot synthesis of ordered and stable cubic mesoporous silica SBA-1 functionalized with amino functional groups”, Microporous and Mesoporous Materials, 2008, in press.

4. Hsien-Ming Kao*, Tzu-Yi Shen, Jyun-Da Wu, Lung-Ping Lee, “Control of ordered structure and morphology of cubic mesoporous silica SBA-1 via direct synthesis of thiol-functionalization”, Microporous and Mesoporous Materials, 2008, in press.

5. Yung-Da Cho, G. T. K. Fey*, Hsien-Ming Kao, “Physical and electrochemical properties of La-doped LiFePO4/C composites as cathode materials for lithium-ion batteries”, J. Solid State Electrochemistry, 2008, in press.

6. Hsien-Ming Kao*, Pai-Ching Chang, Yun-Wen Liao, Lung-Ping Lee, Chu-Hua Chien, “Solid-state NMR characterization of the acid sites in cubic mesoporous Al-MCM-48 materials using trimethylphosphine oxide as a 31P NMR probe”, Microporous and Mesoporous Materials, 2008, in press.

7. C. C. Ting, H. -Y Wu, A. Palani, Anthony S. T. Chiang, Hsien-Ming Kao*“Facile synthesis and morphology control of highly ordered cubic mesoporous silica SBA-1 using short chain dodecyltrimethylammonium chloride as the structure-directing agent”, Microporous and Mesoporous Materials, 2008, in press.

8. Hsien-Ming Kao*, Yi-Chen Liao, “Direct Solid-State NMR Observation of Tetrahedral Aluminum Fluorides in Zeolite HY Fluorinated by Ammonium Fluoride”, J. Phys. Chem. C, 2007, 111, 4495-4498.

9. Hsien-Ming Kao*, “Multinuclear Solid-State NMR, Ionic Dissociation, and Dynamic Properties of Lithium-doped Organic-Inorganic Hybrid Electrolytes Based on Ureasils”, Macromolecules, 2007, 40, 8673-8683.

10. Hsien-Ming Kao*, Yun-Wun Liao, Chun-Chiang Ting, "Synthesis of cubic mesoporous silica SBA-1 with bulky headgroup surfactant cetyltripropylammonium bromide", Microporous and Mesoporous Materials, 2007, 98, 80-88.

11. Ming-Feng Tang, Yi-Hui Liu, Pai-Ching Chang, Yi-Chen Liao, Hsien-Ming Kao and Kwang-Hwa Lii*, “Ionothermal synthesis, crystal structure and solid-state NMR spectroscopy of a new organically templated gallium oxalatophosphate: (H2TMPD)0.5[Ga3(C2O4)0.5(PO4)3] (TMPD = N,N,N’,N’-tetramethyl-1,3-propanediamine)”, Dalton Trans., 2007, 4523–4528.

12. Ling-I Hung, Sue-Lein Wang, Hsien-Ming Kao, and Kwang-Hwa Lii*, “Flux Synthesis, Crystal Structures, and Solid-State NMR Spectroscopy of Indium Silicates Containing Varied In-O Coordination Geometries”, Inorg. Chem., 2007, 46, 3301-3305.

13. G. T. K. Fey*, P. Muralidharan, Y. D. Cho, P. C. Chang, Hsien-Ming Kao, “Electrochemical performance and 7Li NMR studies on an inverse spinel LiNi1/3Co1/3Mn1/3VO4 for Li-ion batteries”, J. Power Sources, 2007, 174, 1142-1146.

14. Hsien-Ming Kao* and Pai-Ching Chang, “Direct Solid-State NMR Spectroscopic Evidence for the Formation of NH4AlF4 Crystalline Phase Derived from Zeolite HY Dealuminated with Ammonium Hexafluorosilicate”, J. Phys. Chem. B, 2006, 110, 19104-19107.

15. Hsien-Ming Kao*, Shih-Wei Chao, and Pai-Ching Chang, “Multinuclear Solid State NMR, Self-Diffusion Coefficients, Differential Scanning Calorimetry and Ionic Conductivity of Solid Organic-Inorganic Hybrid Electrolytes Based on PPG-PEG-PPG Diamine, Siloxane, and Lithium Perchlorate”, Macromolecules, 2006, 39, 1029-1040.

16. Hsien-Ming Kao*, Pai-Ching Chang, Jyun-Da Wu and Anthony S. T. Chiang, “Direct synthesis, characterization and solid-state NMR spectroscopy of large-pore vinyl-functionalized cubic mesoporous silica FDU-12”, Microporous and Mesoporous Materials, 2006, 97, 9-20.

17. Hsien-Ming Kao*, Jyun-Da Wu, and Chun-Chih Cheng, “Direct synthesis of vinyl-functionalized cubic mesoporous silica SBA-1”, Microporous and Mesoporous Materials, 2006, 88, 319-328.

18. Hsien-Ming Kao*, Pai-Ching Chang, and Shih-Wei Chao, “7Li NMR, ionic conductivity and self diffusion coefficients of lithium ion and solvent of plasticized organic-inorganic hybrid electrolyte based on PPG-PEG-PPG diamine and alkoxysilanes”, Electrochimica Acta, 2006, 52, 1015.

19. Hsien-Ming Kao* and Chung-Chih Cheng, “Tetramethoxysilane as a convenient silicon source for phase control of cubic SBA-1 mesostructures”, Materials Letters, 2006, 60, 2594.

20. Tung-Min Wu, Gy-Ron Wu, Hsien-Ming Kao, and Jia-Lin Wang*, “Using mesoporous silica MCM-41 for in-line enrichment of atmospheric volatile organic compounds”, J. Chromatography A, 2006, 1105, 168-175.

21. G. T. K. Fey*, Hsien-Ming Kao, P. Muralidharan, T. P. Kumar, Y. D. Cho, “Electrochemical and solid-state NMR studies on LiCoO2 coated with Al2O3 derived from carboxylate-alumoxane”, J. Power Sources, 2006, 163, 135-143.

22. Hsien-Ming Kao*, Chun-Chiang Ting, Anthony S. T. Chiang, Chih-Chun Teng, and Cheng-Ho Chen, “Facile Synthesis of Stable Cubic Mesoporous Silica SBA-1 over a Broad Synthesis Temperature Range with the Aid of D-Fructose”, Chem. Commun., 2005, 1058-1060.

23. Hsien-Ming Kao*, Chung-Chih Cheng, Chun-Chiang Ting and Li-Yung Hwang, “Phase control of cubic SBA-1 mesostructures via alcohol-assisted synthesis”, J. Mater. Chem., 2005, 15, 2989-2992.

24. Hsien-Ming Kao*, Hsin-Mow Wu, Yun-Wun Liao, Anthony S. T. Chiang, “Aluminosilicate MCM-48 mesostructures assembled from dried zeolite precursors and Gemini surfactant”, Microporous and Mesoporous Materials, 2005, 86, 256-267.

25. Hsien-Ming Kao*, Chun-Chiang Ting, and Shih-Wei Chao, “Post-Synthesis Alumination of Mesoporous Silica SBA-15 with high framework aluminum content using ammonium hexafluoroaluminate”, J. Mol. Catal., A, 2005, 235, 200-208.

26. Hsien-Ming Kao*, Yi-Yuan Tsai, Shih-Wei Chao, “Functionalized mesoporous silica MCM-41 in poly(ethylene oxide)-based polymer electrolytes: NMR and conductivity studies”, Solid State Ionics, 2005, 176/13-14, 1261-1270.

27. Hsien-Ming Kao*, Chien-Liang Chen, and Shih-Wei Chao, “Solid Polymer Electrolyte Based on Pluronic P123 Triblock Copolymer-Siloxane Organic-Inorganic Hybrid”, J. Chin. Chem. Soc., 2005, 52, 693-699.

28. Chen-Hui Liao, Pai-Ching Chang, Hsien-Ming Kao*, and Kwang-Hwa Lii,*, “Synthesis, Crystal Structure, and Solid-State NMR Spectroscopy of a Salt-Inclusion Stannosilicate: [Na3F][SnSi3O9]”, Inorg. Chem., 2005, 44, 9335-9339.

29. Chih-Shan Chen, Hsien-Ming Kao, and Kwang-Hwa Lii*, “K5(UO2)2[Si4O12(OH)]: A Uranyl Silicate Containing Chains of Four Silicate Tetrahedra Linked by SiO---HOSi Hydrogen Bonds”, Inorg. Chem., 2005, 44, 935-940.

30. Chih-Shan Chen, Ray-Kuang Chiang, Hsien-Ming Kao, and Kwang-Hwa Lii*, “High-Temperature, High-Pressure Hydrothermal Synthesis, Crystal Structure, and Solid-State NMR Spectroscopy of Cs2(UO2)(Si2O6) and Variable-Temperature Powder X-ray Diffraction Study of the Hydrate Phase Cs2(UO2)(Si2O6)·0.5H2O”, Inorg. Chem., 2005, 44, 3914-3918.

31. Wang, C.-M.; Liao, C.-H.; Hsien-Ming Kao, Kwang-Hwa Lii*, “Hydrothermal Synthesis and Characterization of [(UO2)2F8(H2O)2Zn2(4,4’-bpy)2]·(4,4’-bpy), A Mixed-Metal Uranyl Aquofluoride with a Pillared Layer Structure”, Inorg. Chem. 2005, 44, 6294-6298.

32. Wen-Jung Chang, Pai-Ching Chang, Hsien-Ming Kao, Kwang-Hwa Lii*, “Synthesis, structural characterization, and solid-state NMR spectroscopy of [Ga(phen)(H1.5PO4)2].H2O and [Ga(phen)(HPO4)(H2PO4)].1.5H2O (phen = 1, 10-phenanthroline), two organic-inorganic hybrid compounds with 1-D chain structures”, J. Solid State Chemistry, 2005, 178, 3709-3715.

33. Hsien-Ming Kao* and Chien-Liang Chen, “An Organic-Inorganic Hybrid Electrolyte Derived from Self-Assembly of Poly(ethylene oxide)-Poly(propylene oxide)-Poly(ethylene oxide) Triblock Copolymer”, Angew. Chem., Int. Ed., 2004, 43, 980-984.

34. Hsien-Ming Kao*, Yun-Chu Chen, Chun-Chiang Ting, Po Tuan Chen, and Jyh-Chiang Jiang, “Characterization of Extraframework Aluminum in H-Mordenite Dealuminated with Ammonium Hexafluorosilicate”, Catalysis Today, 2004, 97, 13-23.

35. Wuu-Jyh Liang, Hsien-Ming Kao*, Ping-Lin Kuo*, “Morphology and Ionic Conductivity Studies of Organic-Inorganic Hybrid Based on Epoxy-crosslinked Polysiloxane/Polyether Networks”, Macromolecular Chemistry and Physics, 2004, 205, 600-610.

36. Kuan-Jiuh Lin*, Shu-Juan Fu, Ching-Yuan Cheng, Wei-Hung Chen, and Hsien-Ming Kao, “New Light on Electrochemical Artificial Muscles: A New Supramolecular Machine Based on One-Dimensional Copper-Containing Organophosphonate System”, Angew. Chem. Int. Ed. 2004, 43, 4186-4189.

37. Ling-I Hung, Sue-Lein Wang, Song-Ping Szu, Chan-Yen Hsieh, Hsien-Ming Kao, and Kwang-Hwa Lii*, “Hydrothermal Synthesis, Crystal Structure, Solid-State NMR Spectrsocopy and Ionic Conductivity of Na5MSi4O12 (M = In, V), Two Silicates Containing a Twelve-Membered Single Ring”, Chem. Mater., 2004, 16, 1660-1666.

38. E. M. Woo*, Yin-Ping Huang, Li Ling Chang, Hsien-Ming Kao, Ru-Rong Wu, Chean-Cheng Su, “Model Compound Study on Network-Forming Reactions between Poly(4-vinyl phenol) and an Epoxy”, Macromolecular Chemistry and Physics: Part B-Physics, 2004, B43, 365-383.

39. Chih-Min Wang, Shiuan-Ting Chuang, Ya-Lan Chuang, Hsien-Ming Kao, and Kwang-Hwa Lii*, “The First Metal Phosphate Incorporating Isonicotinate Ligand: Synthesis, Crystal Structure, and Solid Sate NMR Spectroscopy of Zn(HINT)(HPO4)”, J. Solid State Chem., 2004, 177, 1252-1257.

 

榮譽與經歷

2008 年, 第九屆清華化學科技文教基金會傑出青年學者獎

2008 年, Invited speaker at Rocky Mountain Conference on Solid-State NMR

2006, 2007 年中央大學學術研究傑出獎

2005-2007 台灣磁共振學會理事

2003 年工研院材料所顧問

1999, 2000 年國科會甲種獎

1998 年 Lee Myers Outstanding Graduate Student Award for the academic year 1997-1998, State University of New York at Stony Brook

1988 年台大化學研究所考試榜首

1986 年台大虎氏夫婦獎學金得獎人

1985 – 1987 年台大化學系連續三學期書卷獎
　
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