高憲明 教授（特聘教授）

Hsien-Ming Kao

　

電話: (03) 4227151 分機 65932; 65939; 65937

E-mail: hmkao@cc.ncu.edu.tw

　

台灣大學化學系學士(1988)，台灣大學化學系碩士(1990)，美國紐約州立大學石溪分校化學博士(1998)，美國聖路易市華盛頓大學博士後研究(1998-1999) ，中央大學化學系助理教授(1999-2003)、副教授(2003-2007)、教授(2007-) ，台灣磁共振學會理事 (2005-2007)，中央大學研究傑出獎(2006, 2007)，第九屆清華化學科技文教基金會傑出青年學者獎 (2008)，中央大學貴重儀器中心主任 (2008-)，中央大學特聘教授(2009-)

　

歡迎參觀分子篩觸媒實驗室(03-4227151 分機 65919)

500 MHz Solid State NMR  (03-4227151 分機 65939)

post-doc. position available in Prof. Hsien-Ming Kao's lab

 

研究興趣

1.      奈米孔洞觸媒材料之合成鑑定與其在催化及綠色化學上之應用

2.      高能鋰離子與燃料電池材料之設計開發與應用

3.      奈米複合高分子材料之研發

4.      固態核磁共振技術之開發與應用

                   奈米觸媒

             (中孔洞材料)

電池高能材料

(高分子電解質)

沸石脫鋁

     500 MHz Solid-State NMR

　

　

代表論文 (2011-2008)   2007  2006  2005  2004  2003  2002  2001  2000  1999  1998  1997  1996

70. Hui-Hsu Gavin Tsai, Guang-Liang Jheng and Hsien-Ming Kao*, “Direct Evidence for Interactions between Acidic Functional Groups and Silanols in Cubic Mesoporous Organosilicas”, J. Am. Chem. Soc., 2008, 130, 11566-11567.

71. Hsien-Ming Kao*, Chia-Hsiu Liao, Tzu-Ti Hung, Yu-Chi Pan, Anthony S. T. Chiang, “Direct Synthesis and Solid-State NMR Characterization of Cubic Mesoporous Silica SBA-1 Functionalized with Phenyl Groups”, Chem. Mater., 2008, 20, 2412-2422.

72. Hsien-Ming Kao*, Lung-Ping Lee, Arudra Palani, “13C CPMAS NMR Spectroscopy as a Versatile and Quantitative Tool for Determination of Mercury Adsorption Capacity in Thiol-functionalized Mesoporous Silica SBA-1”, Anal. Chem., 2008, 80, 3016-3019.

73. Chun-Chieh Liao, Hao-Yiang Wu, Diganta Saikia, Yu-Chi Pan, Yu-Kuang Chen, George T. K. Fey and Hsien-Ming Kao*, “A Highly Conductive Star-Branched Organic-Inorganic Hybrid Electrolyte with Remarkable Swelling Properties Based on PPG-PEG-PPG Diamine, Cyanuric Chloride and Alkoxysilane”, Macromolecules, 2008, 41, 8956-8959.

74. Hsien-Ming Kao*, Chia-Hsiu Liao, Arudra Palani, Yi-Chen Liao, “One-pot synthesis of ordered and stable cubic mesoporous silica SBA-1 functionalized with amino functional groups”, Microporous Mesoporous Materials, 2008, 113, 212-223.

75. Hsien-Ming Kao*, Tzu-Yi Shen, Jyun-Da Wu, Lung-Ping Lee, “Control of ordered structure and morphology of cubic mesoporous silica SBA-1 via direct synthesis of thiol-functionalization”, Microporous Mesoporous Materials, 2008, 110, 461-471.

76. Hsien-Ming Kao*, Pai-Ching Chang, Yun-Wen Liao, Lung-Ping Lee, Chu-Hua Chien, “Solid-state NMR characterization of the acid sites in cubic mesoporous Al-MCM-48 materials using trimethylphosphine oxide as a 31P NMR probe”, Microporous Mesoporous Materials, 2008, 114, 352-364.

77. Chun-Chiang Ting, Hao-Yiang Wu, Arudra Palani, Anthony S. T. Chiang, Hsien-Ming Kao* "Facile synthesis and morphology control of highly ordered cubic mesoporous silica SBA-1 using short chain dodecyltrimethylammonium chloride", Microporous Mesoporous Materials, 2008, 116, 323-329.

78. Y. D. Cho, G. T. K. Fey*, Hsien-Ming Kao, “Electrochemical performance of LiFePO4/C composite for Li-ion batteries”, J. Solid-State Electrochemistry, 2008, 12, 815-823.

79. Chung-Ta Tsai, Yu-Chi Pan, Chun-Chiang Ting, Shanmugam Vetrivel, Anthony S. T. Chiang, George T. K. Fey and Hsien-Ming Kao*, “A simple one-pot route to synthesize mesoporous silicas SBA-15 functionalized with exceptional high loadings of pendant carboxylic acid groups”, Chem. Commun., 2009, 5018-5020.

80. Yu-Chi Pan, Hao-Yiang Wu, Guang-Liang Jheng, Hui-Hsu Gavin Tsai* and Hsien-Ming Kao*, “Ordered and Hydrothermally Stable Cubic Periodic Mesoporous Organosilicas with SBA-1 Mesostructures: Synthesis, Characterization, Solid-State NMR Spectroscopy and DFT Calculations”, J. Phys. Chem. C, 2009, 113, 2690-2698.

81. Yu-Chi Pan, Hao-Yiang Wu, Chia-Chun Kao, Hsien-Ming Kao*, Yaw-Nan Shieh, George T. K. Fey, Jen-Hsuan Chang, and Hui-Hsu Gavin Tsai*, “A model system for solid-state NMR study on co-condensation behavior of silicon preursors in periodic mesoporous organosilicas”, J. Phys. Chem. C, 2009, 113, 18251-18258.

82. Diganta Saikia, Hao-Yiang Wu, Yu-Chi Pan, Chun-Chieh Liao, Chien-Fu Chen, George T. K. Fey, and Hsien-Ming Kao*, “A new highly conductive organic-inorganic hybrid electrolyte based on co-condensation of di-ureasil and ethylene glycol-containing alkoxysilane”, Electrochimica Acta, 2009, 54, 7156-7166.

83. Hsien-Ming Kao*, Po-Jui Chiu, Guang-Liang Jheng, Chia-Chun Kao, Chung-Ta Tsai, Hui-Hsu Gavin Tsai*, and Yi-Kang Chou, “Oxidative transformation of thiol groups to disulfide bonds in mesoporous silicas: A diagnostic reaction for probing distribution of organic functional groups”, New J. Chem., 2009, 33, 2199-2203.

84. Hao-Yiang Wu, Chia-Hsiu Liao, Yu-Chi Pan, Chao-Lin Yeh and Hsien-Ming Kao*, “Synthesis and characterization of cubic thiol-functionalized periodic mesoporous organosilicas as effective mercury ion adsorbents”, Microporous Mesoporous Materials, 2009, 119, 109-116.

85. Yu-Chi Pan, Hao-Yiang Wu, Guang-Liang Jheng, George T. K. Fey, and Hsien-Ming Kao*, “Cyanide- and carboxylate-functionalized cubic mesoporous silicas SBA-1: synthesis, characterization and reactivity of organic functional groups”, Microporous Mesoporous Materials, 2009, 123, 78-90.

86. Cheng-Zhang Lu, George Ting-Kuo Fey*, Hsien-Ming Kao, “Study of LiFePO4 cathode materials coated with high surface area carbon”, J. Power Sources, 2009, 189, 155-162.

87. Yung-Da Cho, George Ting-Kuo Fey*, Hsien-Ming Kao, “The effect of carbon coating thickness on the capacity of LiFePO4/C composite cathodes”, J. Power Sources, 2009, 189, 256-262.

88. George Ting-Kuo Fey*, Yun Geng Chen, Hsien-Ming Kao, “Electrochemical properties of LiFePO4 prepared via ball-milling”, J. Power Sources, 2009, 189, 169-178.

89. Chun-Chiang Ting, Hao-Yiang Wu, Shanmugam Vetrivel, Diganta Saikia, Yu-Chi Pan, George T. K. Fey, and Hsien-Ming Kao*, “A one-pot route to synthesize highly ordered mesoporous carbons and silicas through organic-inorganic self-assembly of triblock copolymer, sucrose and silica”, Microporous Mesoporous Materials, 2010, 128, 1-11.

90. Arudra Palani, Hao-Yiang Wu, Chun-Chiang Ting, Shanmugam Vetrivel, Kandaiyan Shanmugapriya, Anthony S. T. Chiang, Hsien-Ming Kao*, “Rapid temperature-assisted sonochemical synthesis of mesoporous silica SBA-15”, Microporous Mesoporous Materials, 2010, 131, 385-392.

91. Hao-Yiang Wu, Ching-Ting Chen, I-Ming Hung, Chia-Hsiu Liao, Shanmugam Vetrivel, and Hsien-Ming Kao*, "Direct Synthesis of Cubic Benzene-Bridged Mesoporous Organosilica Functionalized with Mercaptopropyl Groups as an Effective Adsorbent for Mercury and Silver Ions", J. Phys. Chem. C, 2010, 114, 7021-7029.

92. Shanmugam Vetrivel, Ching-Ting Chen and Hsien-Ming Kao*, “Ultrafast sonochemical synthesis of mesoporous silica MCM-41”, New J. Chem., 2010, 34, 2109-2112.

93. Yuan-Chang Su, Hsien-Ming Kao, Jia-Lin Wang*, “Mesoporous Silicate MCM-48 as an Enrichment Medium for Ambient Volatile Organic Compound Analysis”, J. Chromatography A, 2010, 1217, 5643-5651.

94. Hao-Yiang Wu, Diganta Saikia, Chin-Ping Lin, Feng-Shien Wu, George, T. K. Fey, and Hsien-Ming Kao*, “Synthesis, structure characterization and ionic conductivity of star-branched organic-inorganic hybrid electrolytes based on cyanuric chloride, diamine capped poly(oxyalkylene) and alkoxysilane”, Polymer, 2010, 51, 4351-4361.

95. Chun-Chiang Ting, Hao-Yiang Wu, Yu-Chi Pan, Shanmugam Vetrivel, George T. K. Fey and Hsien-Ming Kao*, "Sugar-Assisted Synthesis of Ordered and Stable Cubic Mesoporous Silica SBA-1", J. Phys. Chem. C, 2010, 114, 19322-19330.

96. Shun-Yi Fangm, Anthony S. T. Chiang*, and Hsien-Ming Kao, "Increasing the Productivity of Colloidal Zeolite Beta by Posthydrolysis Evaporation", Ind. Eng. Chem. Res., 2010, 49, 12191-12196.

97. Diganta Saikia, Hao-Yiang Wu, Yu-Chi Pan, Chi-Pin Lin, Kai-Pin Huang, George T. K. Fey, and Hsien-Ming Kao*, “Electrochemical and Structural Properties of Plasticized Blend Polymer Electrolytes Based on PVdF-HFP, PPG-PEG-PPG Diamine and Methoxy(polyethylenoxy)propyl trimethoxysilane for Li-ion Batteries”, J. Power Sources, 2011, 196, 2826-2834.

98. George Ting-Kuo Fey*, Kai-Pin Huang, Hsien-Ming Kao,  Wen-Hsien Li,  "A polyethylene glycol-assisted carbothermal reduction method to synthesize LiFePO4 using industrial raw materials", J. Power Sources, 2011, 196, 2810-2818.

99. Ching-Shiun Chen*, Chen-Chih Chen, Ching-Ting Chen, Hsien-Ming Kao*, “Synthesis of Cu nanoparticles in mesoporous silica SBA-15 functionalized with carboxylic acid groups”, Chem. Commun., 2011, 47, 2288-2290.

100. Po-Jui Chiu, Shanmugam Vetrivel, Anthony S. T. Chiang, and Hsien-Ming Kao*, "Synthesis and characterization of cubic periodic mesoporous organosilicas with a high loading of disulfide groups", New J. Chem., 2011, 35, 489-494.

101. Wei-Ja Shong*, Chien-Kuo Liu, Chen-Yin Chen, Cheng-Chang Peng, Hui-Jyuan Tu, George Ting-Kuo Fe, Ruey-Yi Lee, and Hsien-Ming Kao, "Effects of Lanthanum-based Perovskite Coatings on the Formation of Oxide Scale for Ferritic SOFC Interconnect", Materials Chemistry and Physics, 2011, 127, 45-50.

102. Chun-Chiang Ting, Chih-Hsuan Chung and Hsien-Ming Kao*, "Direct synthesis of bifunctional periodic mesoporous benzene-silicas functionalized with a high loading of carboxylic acid groups", Chem. Commun., 2011, 47, 5897-5899.

103. Hui-Hsu Gavin Tsai, Po-Jui Chiu, Guang-Liang Jheng, Chun-Chiang Ting, Yu-Chi Pan and Hsien-Ming Kao*, "Synthesis and solid-state NMR characterization of cubic mesoporous silica SBA-1 functionalized with sulfonic acid groups", J. Colloid and Interface Science, 2011, 359, 86-94.

104. Diganta Saikia, Yu-Han Chen, Yu-Chi Pan, Jason Fang, Li-Duan Tsai, George T. K. Fey and Hsien-Ming Kao*, “A new highly conductive organic-inorganic solid polymer electrolyte based on a di-ureasil matrix doped with lithium perchlorate”, J. Mater. Chem., 2011, 21, 10542-10551.

105. Yu-Chi Pan, Diganta Saikia, Jason Fang, Li-Duan Tsai, George T.K. Fey, Hsien-Ming Kao*, “Synthesis and characterization of a new hyperbranched organic–inorganic solid polymer electrolyte with cyanuric chloride as a core element”, Electrochimica Acta, 2011, 56, 8519-8529.

106. G. T. K. Fey*, K. P. Huang, Hsien-Ming Kao and W. H. Li, “A Polyethylene Glycol-Assisted Carbothermal Reduction Method to Synthesize LiFePO4 Using Industrial Raw Materials”, J. Power Sources, 2011, 196, 2810-2818.

107. Tsai-Lung Sung, Yu-Chi Pan, Loganathan Kumaresan, Shanmugam Vetrivel, Hsien-Ming Kao*, “Ultrasonic mediated synthesis of hexagonal benzene-bridged periodic mesoporous organosilicas”, Microporous and Mesoporous Materials, 2012,153, 79-87.

108. Yu-Chi Pan, Hui-Hsu Tsai, Chia-Chun Kao, Tsai-Lung Sung, Po-Jui Chiu, Diganta Saikia, Jen-Hsuan Chang, Hsien-Ming Kao*, “Probing the Nature and Local Structure of Phosphonic Acid Groups Functionalized in Mesoporous Silica SBA-15”, J. Phys. Chem. C, 2012, 116, 1658-1669.

109. G.T.K. Fey*, Y.Y. Lin, K.P. Huang, Y.C. Lin, T.P. Kumar, Y.D. Cho, and Hsien-Ming Kao, “Green energy anode materials: pyrolytic carbons derived from peanut shells for lithium ion batteries”, Adv. Mater. Res., 2012, 415-417, 1572-1585.

110. G. T. K. Fey*, H. J. Tu, K. P. Huang, Y. C. Lin, Hsien-Ming Kao and S. H. Chan, “Particle size effects of carbon sources on electrochemical properties of LiFePO4/C composites”, J. Solid State Electrochem., 2012, in press.

　

榮譽與經歷

2009 年, 中央大學特聘教授

2008 年, 第九屆清華化學科技文教基金會傑出青年學者獎

2008 年, Invited speaker at Rocky Mountain Conference on Solid-State NMR

2008 年-present, 中央大學貴重儀器中心主任

2007-2010 年, 國科會傑出人才養成計畫成員

2006, 2007 年中央大學學術研究傑出獎

2005-2007 台灣磁共振學會理事

2003 年工研院材料所顧問

1999, 2000 年國科會甲種獎

1998 年 Lee Myers Outstanding Graduate Student Award for the academic year 1997-1998, State University of New York at Stony Brook

1988 年台大化學研究所考試榜首

1986 年台大虎氏夫婦獎學金得獎人

1985 – 1987 年台大化學系連續三學期書卷獎

　

書籍著作

1.      普通化學, 第七版 "Introductory Chemistry", 7th Edition, 原著: Steven S. Zumdahl & Donald J. Decoste, 譯者: 高憲明 & 葉玉玲, 學銘圖書有限公司& 歐亞書局有限公司, 2010 年七月出版

2.      何雍, 高憲明 “全方位無機化學”, 第八版

3.      何雍, 高憲明 “物理化學分類題庫”, 第八版

4.      何雍, 高憲明 “儀器分析總整理”, 第八版