Lii, Kwang-Hwa
Position Professor
Name Lii, Kwang-Hwa
Email liikh@cc.ncu.edu.tw
Office Tel No. (03) 4227151 ext. 65930
研究專長 1.Synthesis of metal silicates and germanates by high-temperature, high-pressure hydrothermal reactions and molten flux reactions at high temperature 2.Synthesis of inorganic/organic hybrid compounds with open-framework structures
Autobiography
Autobiography
 
Lii, Kwang-Hwa
B.S. in Chemistry (1976), National Taiwan Normal University
Ph.D. in Inorganic Chemistry (1985), Iowa State University, U.S.A.
Postdoctoral Research Fellow (1986), Exxon Research and Engineering Co., U.S.A.
Associate Research Fellow (1987-1990), Research Fellow(1990-1999),
Institute of Chemistry, Academia Sinica.Professor (1998-), Chairman (1998-2003),
Department of Chemistry, Dean, College of Science (2004-2006),
Dean of Academic Affairs (2006- 2013),
Vice President (2013-2022), National Central University
Distinguished Research Award, National Science Council (1991, 1998, 2003).
Distinguished Scholar Award, Ministry of Education (2004).
National Chair Professorship, Ministry of Education (2007).
Chair Professor, National Central University (2008-)
 
 
 
Research Interests 
1.Synthesis of metal silicates and germanates by high-temperature, high-pressure hydrothermal reactions and molten flux reactions at high temperature
2. Synthesis of metal silicates and borates for nonlinear optical applications


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Selected Publications
  1. Jen, I-H.; Lee, Y.-C.; Tsai, C.-E.; Lii, K-H., “Edge-Sharing BO4 Tetrahedra in the Structure of Hydrothermally Synthesized Barium Borates: a-Ba3[B10O17(OH)2]”, Inorg. Chem. 2019, 58, 4085-4088. 
  2. Liao, C.-J.; Wen, Y.-S.; Lii, K.-H., “High-Temperature, High-Pressure Hydrothermal Synthesis of Ba3[B6O10(OH)2](CO3) and Ba6[B12O21(OH)2](CO3)2, Two Barium Borate Carbonates with 2D Layer and 3D Framework Structures”, Inorg. Chem. 2018, 57, 11492-11497.
  3. Chao, T.-L.; Chang, W.-J.; Wen, S.-H.; Lin, Y.-Q.; Chang, B.-C.; Lii, K.-H., “Titanosilicates with Strong Phase-Matched Second Harmonic Generation Responses”, J. Am. Chem. Soc. 2016, 138, 9061-9064.
  4. Liu, C.-L.; Liu, H.-K.; Chang, W.-J.; Lii, K.-H., “K2Ca4[(UO2)(Si2O7)2]: A Uranyl Silicate with a One-Dimensional Chain Structure”, Inorg. Chem. 2015, 54, 8165-8167.
  5. Lin, H.-Y.; Chin, C.-Y.; Huang, H.-L.; Huang, W.-Y.; Sie, M.-J.; Huang, L.-H.; Lee, Y.-H.; Lin, C.-H.; Lii, K.-H.; Bu, X.-H.; Wang, S.-L., “Crystalline Inorganic Frameworks with 56-Ring, 64-Ring, and 72-Ring Channels”, Science 2013, 339, 811-813.
  6. Liu, H.-K.; Lii, K.-H., “Mixed-Valence Uranium(V,VI) and Uranyl Oxyhydroxides Synthesized under High-Temperature, High-Pressure Hydrothermal Conditions: Na5[U5O16(OH)2] and Na5[U5O17(OH)]”, Inorg. Chem. 2013, 52, 9172-9174.
  7. Nguyen, Q. B.; Chen, C.-L.; Chiang, Y.-W.; Lii, K.-H., “Cs3UGe7O18: A Pentavalent Uranium Germanate Containing Four and Six-Coordinate Germanium”, Inorg. Chem. 2012, 51, 3879-3882.
  8. Liu, H.-K.; Lii, K.-H., “Cs2USi6O15: A Tetravalent Uranium Silicate”, Inorg. Chem. 2011, 50, 5870-5872.
  9. Lee, C.-S.; Lin, C.-H.; Wang, S.-L.; Lii, K.-H., “Na7UIVO2(UVO)2(UV/VIO2)2Si4O16: An Extraordinary Mixed-Valence Uranium Silicate”, Angew. Chem. Int. Ed. 2010, 49, 4254 –4256 
  10. Lee, C.-S.; Wang, S.-L.; Lii, K.-H.,“Cs2K(UO)2Si4O12: A Mixed-Valence Uranium(IV,V) Silicate”, J. Am. Chem. Soc. 2009, 131, 15116-15117. 
  11. Lin, C.-H.; Chiang, R.-K.; Lii, K.-H., “Synthesis of Thermally Stable Extra-Large Pore Crystalline Materials: A Uranyl Germanate with 12-Ring Channels”, J. Am. Chem. Soc. 2009, 131, 2068-2069. 
  12. Lin, C.-H.; Lii, K.-H., “A3(U2O4)(Ge2O7) (A = Rb, Cs): Mixed-Valence Uranium(V,VI) Germanates”, Angew. Chem. Int. Ed. 2008, 47, 8711-8713. 
  13. Lai, Y.-L.; Lii, K.-H.; Wang, S.-L., “26-Ring-Channel Structure Constructed from Bimetal Phosphite Helical Chains“, J. Am. Chem. Soc. 2007, 129, 5350-5351. 
  14. Chen, C.-S.; Lee, S.-F.; Lii, K.-H., “K(UO)Si2O6: A Pentavalent-Uranium Silicate”, J. Am. Chem. Soc. 2005, 127, 12208-12209.