職稱 | 教授 |
---|---|
姓名 | 陳銘洲 |
電子郵件 | |
Phone: | (03) 4227151 ext. 65943 |
專業領域 | 觸媒 、高分子、有機材料化學 |
國家 | 學校名稱 | 系所 | 學位 |
---|---|---|---|
臺灣 | 彰化師範大學 | 化學系 | 學士 |
臺灣 | 臺灣大學 | 化學系 | 碩士 |
美國 | 加州大學聖地牙哥分校 | 化學系 | 博士 |
服務機關名稱 | 單位 | 職務 | 期間 |
---|---|---|---|
國立中央大學 | 化學系 | 主任 | 2018.08 ~ 2021.07 |
國立中央大學 | 化學系 | 教授 | 2015.08 ~ 迄今 |
國立中央大學 | 化學系 | 副教授 | 2011.01 ~ 2015.01 |
國立中央大學 | 化學系 | 助理教授 | 2004.01 ~ 2011.01 |
美國西北大學 | 博士後研究 | 1999.01 ~ 2004.01 | |
美國加州大學柏克萊分校 | 博士後研究 | 1998.01 ~ 1999.01 |
類別 | 年度 | 獎項名稱 | 頒獎單位 |
---|---|---|---|
校內榮譽 | 2024 | 傑出論文貢獻獎 | 中央大學 |
校內榮譽 | 2024 | 傑出產學貢獻獎 | 中央大學 |
校內榮譽 | 2024 | 中央大學教學優良獎 | 中央大學 |
校內榮譽 | 2023 | 拔尖產學貢獻獎 | 中央大學 |
校內榮譽 | 2023 | 傑出論文貢獻獎 | 中央大學 |
校外榮譽 | 2017 | 科技部大專學生研究計畫105年度研究創作獎 | 科技部 |
校內榮譽 | 2013 | 102年度中央大學服務學習傑出導師 | 中央大學 |
校內榮譽 | 2011 | 100年度中央大學優良導師 | 中央大學 |
本實驗室這幾年以開發電性良好之p-型和n-型有機半導體材料為主要目標,2017發表一可溶性p-型材料噻吩材料其元件利用溶液製程具1.7 cm2V-1s-1之高電性效能 (Adv. Mater. 2017),之後開發出可溶性材料具>2.6與3.5 cm2V-1s-1(分別於Chem. Mater.2020與ACS Nano 2021)。近期發表一可溶性噻吩材料具>4.0 cm2V-1s-1之高電性效能 (Adv. Funct. Mater. 2022),這幾個可溶性材料皆為當年度臺灣所開發之p-型小分子材料之最高溶液製程電性記錄。
N-型有機半導體材料開發方面,2017首度發表一可溶性併環噻吩材料元件利用溶液製程具0.3 cm2V-1s-1之效能 (Adv. Funct. Mater. 2017),之後開發兩可溶性n-型材料利用溶液製程具0.77與2.54 cm2V-1s-1之高電性,分別於ACS AMI 2020 & Adv. Science 2021發表,於台灣本土開發之可溶性小分子n-型OTFT材料中首屈一指。目前已將這一些小分子應用於鉛鈣鈦礦太陽能電池,元件效能具21.39% PCE 於 JMCA 2022 發表,元件具 22.2% 於 ACS AMI 2024 發表,近期一材料的元件效能已達~23.71% PCE (整稿中)。
利用本實驗室所開發之兩個高電性之p型與n型可溶性材料,以溶液製程製備之ambipolar元件,p-型與n-型電性分別可達0.83與0.37 cm2V-1s-1,為全球最高小分子以溶液製程所得之ambipoar OTFT電性紀錄。本實驗室今年已開發一個ambipolar材料,p-型與n-型電性分別可達0.46與0.33 cm2V-1s-1,為全台單一小分子以溶液製程所得之ambipoar OTFT最高電性紀錄。本實驗室正與合作者努力,期將此類ambipolar材料應用於鈣鈦礦太陽能電池中。
本實驗室開發之有機共軛單元,亦可應用於DSSC/OPV/PSC等有機光電材料的開發。本實驗已開發兩有機染敏材料(DSSC)之光電轉換效能具10.1% (JACS 2015)與11.2% (JMCA 2017)-皆為當時全台最高光電轉換效能記錄之有機染敏材料。近期,本實驗室已開發有機染敏作為有機電洞傳輸層材料應用於錫鈣鈦礦太陽能電池(Sn-PSC),元件效能具~8.3% PCE(發表於Adv. Fucnt. Mater. 2023)。近期我們已另開發有機染敏自組裝SAM材料(作為HTM)材料應用於Sn-PSC,兩材料具7.7%與8.1% PCE已分別於今年的Angew. Chem. Int. Ed. 與 Small 發表。目前有三個系列的SAM材料於Sn-PSC具8.6% (ACS AMI 即將發表)、8.7% PCE (ACS EL 備稿中) 與9.5% PCE (備稿中)。新開發的幾個SAM材料,亦可以應用於Pb-PSC,其中一個系列已展現23.5% PCE。亦另有一系列於弱光下,更展現~40%的高光電轉換效能。(這五個成果將於近期發表)
本實驗室亦早開發有機電洞傳輸層材料(HTM)材料應用於Sn-PSC,兩材料具7.23%與7.59% PCE分別於 JACS 2018 與 Adv. Funct. Mater. 2019 發表。2023跨足開發高分子有機電洞傳輸層材料應用於Sn-PSC具~7.6%之效能(Adv. Mater. 2023),之後開發新高分子HTM具8.6% PCE,為目前全球Sn-PSC之最高效能之高分子HTM (Adv. Energy Mater. 2023)。
本實驗室亦開發HTM材料應用於Pb-PSC,兩材料具~19.3% PCE於 Small 2021及 Chem. Mater. 2021發表。之後,兩系列材料具~20.2% PCE已分別於ACS Energy Letters與ACS AMI 2022發表。2023年,本實驗發表一材料具~21.7% PCE。
本實驗室近期已著手開發n-型電子傳輸層材料應用於PSC,其中一系列分子之效能可達23.68% PCE(即將投稿) ,另有幾系列分子已具不錯效能> 22 % PCE。
本實驗室亦開發新非富勒烯(NFA)材料應用於有機光伏電池(OPV),其中兩系列分子之效能可達~16.2%-16.6% PCE,已發表於近期之 JMCC。本實驗室所開發之NFA材料亦已應用於Pb-PSC,具~21.4% PCE於 JMCA 2022發表,具~22.2% PCE亦已發表於ACS AMI 2024。近期一新NFA材料應用於Pb-PSC已具~23.71% PCE (即將投稿)。
Figure 1. 陳銘洲實驗室所發表之較具代表性文章整理.
- 2024年-開發出小分子自組裝(SAM)電洞傳輸層(HTM)材料應用於錫鈣鈦礦太陽能電池(Sn-PSC),光電轉換效率(PCE)達7.7%,發表於Angew. Chem. Int. Ed. (IF:16.1)
- 2024年-開發出全台最高雙性有機薄膜電晶體小分子材料,發表於Adv. Science (被引用次數7)
- 2023年-開發出高分子HTM材料應用於Sn-PSC具8.6%PCE,為目前全球Sn-PSC最高效能之高分子HTM,發表於Adv. Energy Mater. (IF:24.4;被引用次數15).
- 2023年-開發出高分子HTM應用於Sn-PSC具7.6%PCE,為當時全球最高效能,發表於Adv. Mater. (IF:27.4;被引用次數30).
- 2023年-開發出X-型自組裝分子作為HTM應用於Sn-PSC,為目前全球Sn-PSC最高效能之SAM,發表於Adv. Funct. Mater. (IF:18.5;被引用次數35).
- 2022年-發表全台最高p-型效能之小分子OTFT材料,元件之mobility高達4.01cm2V-1s-1(Adv. Funct. Mater. ;為全台溶液製程最高效能,被引用次數38)
- 2021年-發表全台最高n-型效能之小分子OTFT材料,元件mobility 高達2.56cm2V-1s-1(Adv. Science;為全台溶液製程最高n-型效能,被引用次數35)
- 2021年-發表全台最高p-型效能之小分子OTFT材料,元件mobility高達3.2 cm2V-1s-1(ACS Nano; IF:15.8,被引用次數27)
- 2020年-發表全台最高p-型效能之小分子OTFT材料,元件mobility 高達2.6 cm2V-1s-1(Chem. Mater.;被引用次數47)
- 2019年-發表全台最高效能HTM於Sn-PSC具7.6%PCE(Adv. Funct. Mater. ;被引用次數64)
即將發表:
2024年-開發出小分子自組裝(SAM)電洞傳輸層(HTM)材料應用於錫鈣鈦礦太陽能電池(Sn-PSC),光電轉換效率(PCE)達8.4%,Small in press.
以通訊作者發表之文章(自2019至今):
- Dyes and Pig. 2019, 725 (IF:4.1)
- Phy. Chem. Chem. Phy. 2019, 21, 3960 (IF:2.9)
- Adv. Funct. Mater. 2019, 1905393 (IF:18.5)
- ACS Appl. Mater. Inter., 2020. 12, 15071 (IF:8.3)
- Chem. Mater. 2020, 32, 1422 (IF:7.2)
- ACS Appl. Mater. Inter. 2020. 12, 25081
- J. Mater. Chem. C 2020, 8, 15450 (IF:5.7)
- J. Mater. Chem. C 2020, 8,15322
- ACS Nano 2021, 15, 727 (IF:15.8)
- Advanced Science 2021, 2002930 (IF:14.3)
- Adv. Mater. Tech. 2021, 2001028 (IF:6.4)
- Small 2021, 2100783 (IF:13.0)
- Chem. Mater. 2021, 33, 3286 (IF:7.2)
- Adv. Electron. Mater. 2022, 2100648 (IF:5.3)
- ACS Appl. Energy Mater. 2022, 5, 4149. (IF:5.4)
- Adv. Opt. Mater. 2022, 10, 2102650 (IF:8.0)
- Adv. Funct. Mater. 2022, 32, 2200880 (IF:18.5)
- ACS Appl. Mater. Inter. 2022, 14, 22053
- J. Mater. Chem. A 2022, 10, 11254 (IF:10.7)
- ACS Energy Lett. 2022, 7, 2118 (IF:19.3)
- J. Phy. Chem. C 2022, 126, 12906 (IF:3.3)
- J. Chin. Chem. Soc. 2022, 69, 1253 (IF:1.6)
- J. Mater. Chem. C 2022, 10, 14496 (IF:5.7)
- Cell Reports Phy. Sci. 2023, 4, 101312 (IF:7.9)
- Chem. Engineering J. 2023, 458, 141366 (IF:13.3)
- Adv. Funct. Mater. 2023, 2213939 (IF:18.5)
- Adv. Mater. 2023, 35, 2300681(IF:27.4)
- Adv. Energy Mater. 2023, 2302047(IF:24.4)
- J. Chin. Chem. Soc. 2023, 70, 2046
- ACS Appl. Mater. Inter. 2024, 16, 6162
- J. Mater. Chem. C 2024, 12, 2247
- J. Mater. Chem. C 2024, 12, 3482
- Adv. Science 2024, 2305361 (IF:14.3)
- Angew. Chem. Int. Ed. 2024. 63, e202407228. (IF:16.1)
- S. Vegiraju, B.-C. Chang, L.-H. Li, D.-Y. Huang, K.-Y. Wu, P. Priyanka, W.-C. Chang, Y.-Y. Lai, B.-C. Yu, C.-L. Wang, C.-L. Liu, Ming-Chou Chen, A. Facchetti.”Intramolecular Locked Dithioalkylbithiophene Based Semiconductors for High Performance Organic Field Effect Transistors.”Adv. Mater. 2017, 1702414 (CTI: 31)
- S. Vegiraju, G.-Y. He, C. Kim, P. Priyanka, Y.-J. Chiu, C.-W. Liu, C.-Y. Huang, J.-S. Ni, Y.-W. Wu, Z. Chen, G.-H. Lee, S.-H. Tung, C.-L. Liu, Ming-Chou Chen, and A. Facchetti.”Solution-Processable Dithienothiophenoquinoid (DTTQ) Structures for Ambient-Stable n-Channel Organic Field Effect Transistors.”Adv. Funct. Mater. 2017, 1606761 (CTI: 22)
- Y. Ezhumalai, B. Lee, M.-S. Fan, B. Harutyunyan, K. Prabakaran, C.-P. Lee, S. H. Chang, J.-S. Ni, S. Vegiraju, P. Priyanka, Y.-W. Wu, C.-W. Liu, S. Yau, J. T. Lin, C.-G. Wu, M. J. Bedzyk, R.P. H. Chang, Ming-Chou Chen, K.-C. Ho , T. J. Marks.”Metal-free branched alkyl tetrathienoacene (TTAR) based sensitizers for high-performance dyesensitized solar cells.”J. Mater. Chem. A 2017, 12310 (CTI: 46)
- S. Vegiraju, D.-Y. Huang, P. Priyanka, Y.-S. Li, X.-L. Luo, S.-H. Hong, J.-S. Ni, S.-H. Tung, C.-L. Wang, W.-C. Lien, S. L. Yau, C.-L. Liu , Ming-Chou Chen.”High Performance Solution-processable Tetrathienoacene (TTAR) based Small Molecules for Organic Field Effect Transistors (OFETs).”Chem. Commun. 2017, 5898 (CTI: 24)
- B.-Y. Jiang, S. Vegiraju, A. S.-T. Chiang, Ming-Chou Chen, C.-L. Liu.”Low-voltage-driven organic phototransistors based on a solution-processed organic semiconductor channel and high k hybrid gate dielectric.”J. Mater. Chem. C 2017, 5, 9838. (CTI: 6)
- N. C. Mamillapalli, S. Vegiraju, P. Priyanka, C.-Y. Lin, X.-L. Luo, H.-C. Tsai, S.-H. Hong, J.-S. Ni, W.-C. Lien, G. Kwon, S. Yau , C. Kim , C.-L. Liu , Ming-Chou Chen.”Solution-Processable End-functionalized Tetrathienoacene Semiconductors: Synthesis, Characterization and Organic Field Effect Transistors Applications.”Dyes and Pigments 2017, 145, 584. (CTI: 12)
- W. Ke, P. Priyanka, S. Vegiraju, C. C. Stoumpos, I. Spanopoulos, C. M. M. Soe, T. J. Marks, Ming-Chou Chen, M. G. Kanatzidis.”Dopant-Free Tetrakis-triphenylamine Hole Transporting Material for Efficient Tin-Based Perovskite Solar Cells.”J. Am. Chem. Soc. 2018, 140, 388. (CTI: 123)
- S. Vegiraju, C.-Y. Lin, P. Priyanka, D.-Y. Huang, X.-L. Luo, H.-C. Tsai, S.-H. Hong, C.-J. Yeh, W.-C. Lien, C.-L. Wang, S.-H. Tung, C.-L.Liu, Ming-Chou Chen, A. Facchetti.”Solution-Processed High-Performance Tetrathienothiophene Based Small Molecular Blends for Ambipolar Charge Transport.”Adv. Funct. Mater. 2018, 1801025. (CTI:14)
- S. Vegiraju, C.-Y. Lin, P. Priyanka, D.-Y. Huang, X.-L. Luo, H.-C. Tsai, S.-H. Hong, C.-J. Yeh, W.-C. Lien, C.-L. Wang, S.-H. Tung, C.-L.Liu, Ming-Chou Chen, A. Facchetti.”Solution-Processed High-Performance Tetrathienothiophene Based Small Molecular Blends for Ambipolar Charge Transport.”Adv. Funct. Mater. 2018, 1801025. (CTI:14)
- S. Vegiraju, W. Ke, P. Priyanka, N. J-S, W. Y-C, S. Ioannis, Y. S-L, T.J. Marks , Ming-Chou Chen, M. G. Kanatzidis.“Benzodithiophene Hole-Transporting Materials for Efficient Tin-Based Perovskite Solar Cells.”Adv. Funct. Mater. 2019, 1905393 (CTI: 31)
- S. Vegiraju, X.-L, Luo, L.-H. Li, S. N. Afraj, C. Lee, D. Zheng, H.-C. Hsieh,C.-C. Lin, S.-H. Hong, H.-C. Tsai, G.-H. Lee, S.-H. Tung, C.-L. Liu, Ming-Chou Chen, A. Facchetti.”Solution processable pseudo n-thienoacenes via intramolecular S···S lock for high performance organic field effect transistors.”Chem. Mater. 2020, 32(4), 1422-1429. (CTI: 21)
- Y. Ezhumalai, F.-S. Lin, M.-S. Fan, K. Prabakaran, J.-S. Ni, Y.-C. Wu, G.-H. Lee, Ming-Chou Chen, K.-C. Ho.”Thioalkyl-Functionalized Bithiophene (SBT)-Based Organic Sensitizers for High-Performance Dye-Sensitized Solar Cells.”ACS Applied Materials & Interfaces 2020, 12, 15071 (CTI: 14)
- S. Vegiraju, A. A. Amelenan Torimtubun, P.-S. Lin, H.-C. Tsai, W.-C. Lien, C.-S. Chen, G.-Y. He, C.-Y. Lin, D. Zheng, Y.-F. Huang, Y.-C. Wu, S.-L. Yau, G.-H. Lee, S.-H. Tung, C.-L. Wang, C.-L. Liu, Ming-Chou Chen, A. Facchetti.”Solution-Processable Quinoidal Dithioalkylterthiophene-Based Small Molecules Pseudo-Pentathienoacenes via an Intramolecular S···S Lock for High-Performance n-Type Organic Field-Effect Transistors.”ACS Applied Materials & Interfaces 2020, 12, 25081 (CTI: 15)
- F.-S. Lin, P. Priyanka, M.-S. Fan, S. Vegiraju, J.-S. Ni, Y.-C. Wu, Y.-H. Li, G.-H. Lee,Y. Ezhumalai, R.-J. Jeng, Ming-Chou Chen, K.-C. Ho.”Metal-free efficient dye-sensitized solar cells based on thioalkylated bithiophenyl organic dyes.” J. Mater. Chem. C 2020, 8, 15322 (CTI: 11)
- V. Joseph, C.-H. Yu, C.-C. Lin, W.-C. Lien, H.-C. Tsai, C.-S. Chen, A. A. Amelenan Torimtubun, A. Velusamy, P.-Y. Huang, G.-H. Lee, S.-L. Yau, S.-H. Tung, T. Minari, C.-L. Liu , Ming-Chou Chen. “Quinoidal thioalkyl-substituted bithiophene small molecule semiconductors for n-type organic field effect transistors.”J. Mater. Chem. C 2020, 8, 15450--15458 (CTI: 6)
- A. Velusamy, C.-H. Yu, S. N. Afraj, C.-C. Lin, W.-Y. Lo, C.-. Yeh, Y.-W. Wu, H.-C. Hsieh, J. Chen, G.-H. Lee, S.-H. Tung, C.-L. Liu, Ming-Chou Chen, A. Facchetti “Thienoisoindigo (TII)-Based Quinoidal Small Molecules for High-Performance n-Type Organic Field Effect Transistors.”Advanced Science 2020, 2002930 (CTI: 13)
- C.-C. Lin, S. N. Afraj, A. Velusamy, P.-C. Yu, C.-H. Cho, J. Chen, Y.-H. Li, G.-H. Lee, S.-H. Tung, C.-L. Liu, Ming-Chou Chen, A. Facchetti “A Solution Processable 3,5 Dithioalkyl Dithienothiophene (DSDTT) Based Small Molecule and its Blends for High Performance p-type Organic Field Effect Transistors.”ACS Nano 2020, 15 727 (CTI: 9)
- S. N. Afraj, G.-Y. He, C.-Y,. Lin, A. Velusamy, C.-Y. Huang, S. Vegiraju, P.-Y. Huang, J.-S. Ni, S.-L. Yau, S.-H. Tung, T. Minari, C.-L. Liu, Ming-Chou Chen “Solution-processable multi-fused thiophene small molecules and conjugated polymer semiconducting blend for organic field effect transistor application.”Advanced Materials Technologies 2021, 2001028 (CTI: 8)
- V. Joseph, A. A. Sutanto, C. Igci, O. A. Syzgantseva, V Jankauskas, K. Rakstys, V. I.E. Queloz, H. Kanda, P.-Y Huang, J-S. Ni, S. Kinge, Ming-Chou Chen, M. K. Nazeeruddin “Stable Perovskite Solar Cells Using Molecularly Engineered Functionalized Oligothiophenes as Low-cost Hole-transporting Materials.”Small 2021, 2100783 (CTI: 9)
- A. A. Sutanto, V. Joseph, C. Igci, O.A. Syzgantseva, M. A. Syzgantseva, V. Jankauskas, K. Rakstys, V. I.E. Queloz, P.-Y. Huang, J.-S. Ni, S. Kinge, A. M. Asiri, Ming-Chou Chen, M. K. Nazeeruddin “Isomeric carbazole-based hole-transporting materials: Role of linkage position on the photovoltaic performance of perovskite solar cells.”Chem. Mater. 2021, 33, 3286 (CTI: 12)
- P.-S. Lin, Y. Shoji, S. N. Afraj, M. Ueda, C.-H. Lin, S. Inagaki, T. Endo, S.-H. Tung, Ming-Chou Chen, C.-L. Liu, T. Higashihara “Controlled Synthesis of Poly[(3-alkylthio)thiophene]s and Their Application to Organic Field-Effect Transistors.”ACS Applied Materials & Interfaces 2021, 13, 31898 (CTI: 9)
- A. Velusamy, Y.-C. Yang, C.-C. Lin, S. N. Afraj, K. Jiang, P.-S. Chen, S.-L. Yau, I. Osaka, S.-H. Tung, Ming-Chou Chen, C.-L. Liu “Solution Processable Pentafluorophenyl End-Capped Dithienothiophene Organic Semiconductors for Hole-Transporting Organic Field Effect Transistors.”Adv. Electron. Mater. 2021, 2100648 (CTI: 1)
- T.-W. Chen, S. N. Afraj, S.-H. Hong, L.-H Chou, A. Velusamy, C.-Y. Chen, Y. Ezhumalai, S.-H. Yang, I. Osaka, X.-F. Wang, Ming-Chou Chen, C.-L. Liu “Synergetic Effect on Enhanced Photovoltaic Performance of Spray- Coated Perovskite Solar Cells Enabled by Additive Doping and Antisolvent Additive Spraying Treatment.”ACS Appl. Energy Mater. 2022, 5, 4149. (I.F. ~6; CTI: 2)
- C.-C. Lin, A. Velusamy, S.-H. Tung, I. Osaka, Ming-Chou Chen, C.-L. Liu “Tunable Photoelectric Properties of N-type Semiconducting Polymer:Small Molecule Blends for Red Light Sensing Phototransistors.”Adv. Opt. Mater. 2022, 10, 2102650. (I.F. ~9.926; CTI: 1)
- S. N. Afraj, C.-C. Lin, A. Velusamy, C.-H. Cho, H.-Y. Liu, J. Chen, G.-H. Lee, J.-C. Fu, J.-S. Ni, S.-H. Tung, S. Yau, C.-L. Liu, Ming-Chou Chen, A. Facchetti “Heteroalkyl-Substitution in Molecular Organic Semiconductors. Chalcogen Effect on Crystallography, Conformational Lock and Charge Transport.”Adv. Funct. Mater. 2022, 32, 2200880. (CTI: 6)
- V. Joseph, J. Xia, A. A. Sutanto, V. Jankauskas, C. Momblona, B. Ding, K. Rakstys, R. Balasaravanan, C.-H. Pan, J.-S. Ni, S.-L. Yau, M. Sohail, Ming-Chou Chen, P. J. Dyson, M. K. Nazeeruddin “Triarylamine-Functionalized Imidazolyl-Capped Bithiophene Hole Transporting Material for Cost-Effective Perovskite Solar Cells.”ACS Applied Materials & Interfaces 2022, 14, 22053. (CTI: 1)
- S. N. Afraj, A. Velusamy, C.-Y. Chen, J.-S. Ni, Y. Ezhumalai, C.-H. Pan, K.-Y. Chen, S.-L. Yau, C.-L. Liu, C.-H. Chiang, C.-G. Wu, Ming-Chou Chen”Dicyclopentadithienothiophene (DCDTT)-based organic semiconductor assisted grain boundary passivation for highly efficient and stable perovskite solar cells.”J. Mater. Chem. A 2022, 10, 11254. (CTI: 2)
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